| Edem Frederic Hegbe, Ambassador 2017 – à nos jours |
| Yokoudèma Kadokalih, Counselor, Chargé d’Affaires ad interim 2015 – 2017 |
| Limbiye Kadangha Bariki, Ambassador 2009 – 2015 |
| Lorempo Tchabre Landjergue, Minister-Counselor, Chargé d’Affaires ad interim 2007 – 2009 |
| Mrs. B. Mayanendja Nonon Saa Wolou, Minister-Counselor, Chargé d’Affaires ad interim 2005 – 2007 |
| Akoussoulélou Bodjona, Ambassador 1999 – 2005 |
| Kossivi Osseyi, Ambassador 1995 – 1999 |
| Edem Frederic Hegbe, Counselor, Chargé d’Affaires ad interim 1993 – 1995 |
| Ellom-Kodjo Schuppius, Ambassador 1983 – 1993 |
| Yao Grunitzky, Ambassador 1979 – 1983 |
| Messanvi Kokou Kekeh, Ambassador 1974 – 1979 |
| Epiphane Avi Mawussi, Ambassador 1971 – 1974 |
| Dr. Alexandre Ohin, Ambassador 1967 – 1971 |
| Dr. Robert Ajavon, Ambassador 1964 – 1967 |
| John Dossé Abalom First Secretary, Chargé d’Affaires ad interim 1963 – 1964 |
| André Akakpo, Ambassador 1960 – 1963 |